ENOLIZATION REACTIONS MEDIATED BY S-BLOCK METAL AMIDE REAGENTS

ENOLIZATION REACTIONS MEDIATED BY S-BLOCK METAL AMIDE REAGENTS

Performance of Alkali and Alkaline Earth Metal Amides in Enolization of Ketones and the Mechanism behind E-stereoselectivity in non-polar solvents

LAP Lambert Academic Publishing ( 2009-03-01 )

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The enolization of ketonic substrates is a cornerstone reaction in modern organic synthesis. The research in this book is split into three main sections, with the investigation of s-block metal enolate chemistry being the underlying theme: The first section focuses on the synthesis and characterization of a series of homo- and heterobimetallic potassium and calcium enolates. The second section concentrates on an investigation into the utility of Ca(HMDS)2 to mediate the enolization of ketonic substrates. The final section outlines a detailed mechanistic study for the enolization of propiophenone mediated by Mg(HMDS)2 in toluene.

Book Details:

ISBN-13:

978-3-8383-0016-0

ISBN-10:

3838300165

EAN:

9783838300160

Book language:

English

By (author) :

Xuyang He

Number of pages:

220

Published on:

2009-03-01

Category:

Chemistry